化學纖維主要紡絲方法之一,簡稱濕紡。濕紡包括的工序是:(1)製備紡絲原液;(2)將原液從噴絲孔壓出形成細流;(3)原液細流凝固成初生纖維;(4)初生纖維卷裝或直接進行後處理。 將成纖高聚物溶解在適當的溶劑中,得到一定組成、yidingzhandubingjuyoulianghaokefangxingderongye,chengfangsiyuanye。yekeyoujunxiangrongyejuhezhijiededaofangsiyuanye。gaojuwuzairongjieqianxianfashengrongzhang,jirongjixianxianggaojuwuneibushenru,shidafenzizhijiandejulibuduanzengda,ranhourongjiexingchengjunyunderongye。zhenggeguochengsuoxushijianhenchang,rongzhangguochengdesududuirongjiesuduyouzhongyaoyingxiang。gaojuwurongyezaifangsizhiqian,xujinghunhe、guolvhetuopaodengfangqianzhunbeigongxu,yishifangsiyuanyedexingzhijunyunyizhi,chuquqizhongsuojiadaideningjiaokuaihezazhibingtuochuyezhongdeqipao。zaizhanjiaoxianweishengchanzhong,fangqianzhunbeihaibaokuoshuchenggongxu,shizhanjiaojuyoubiyaodekefangxing。 紡絲原液被循環管道送至紡絲機,通過計量泵計量,然後經燭形濾器、連接管而進入噴絲頭(帽)。噴絲頭一般采用黃金與鉑的合金或鉭合金材料製成。在噴絲頭上有規律地分布若幹孔眼,孔徑為0.05~0.08毫hao米mi。從cong噴pen絲si孔kong眼yan中zhong壓ya出chu的de原yuan液ye細xi流liu進jin入ru凝ning固gu浴yu,原yuan液ye細xi流liu中zhong的de溶rong劑ji向xiang凝ning固gu浴yu擴kuo散san,凝ning固gu劑ji向xiang細xi流liu滲shen透tou,從cong而er使shi原yuan液ye細xi流liu達da到dao臨lin界jie濃nong度du,在zai凝ning固gu浴yu中zhong析xi出chu而er形xing成cheng纖xian維wei。濕shi紡fang中zhong的de擴kuo散san和he凝ning固gu是shi物wu理li化hua學xue過guo程cheng,但dan某mou些xie化hua學xue纖xian維wei在zai濕shi紡fang過guo程cheng中zhong還hai同tong時shi發fa生sheng化hua學xue變bian化hua。例li如ru粘zhan膠jiao纖xian維wei,纖xian維wei素su黃huang酸suan納na分fen解jie成cheng為wei纖xian維wei素su再zai生sheng纖xian維wei。 濕法紡絲速度(指卷取初生纖維的第一導絲盤速度)由(you)於(yu)受(shou)溶(rong)劑(ji)和(he)凝(ning)固(gu)劑(ji)雙(shuang)擴(kuo)散(san)速(su)度(du)和(he)凝(ning)固(gu)浴(yu)的(de)流(liu)體(ti)阻(zu)力(li)等(deng)限(xian)製(zhi),因(yin)此(ci)遠(yuan)比(bi)熔(rong)紡(fang)速(su)度(du)為(wei)低(di)。第(di)一(yi)導(dao)絲(si)盤(pan)的(de)線(xian)速(su)度(du)與(yu)紡(fang)絲(si)原(yuan)液(ye)的(de)擠(ji)出(chu)速(su)度(du)之(zhi)比(bi)稱(cheng)為(wei)噴(pen)絲(si)頭(tou)拉(la)伸(shen)比(bi)。濕(shi)紡(fang)拉(la)伸(shen)比(bi)一(yi)般(ban)為(wei)負(fu)值(zhi)、零,或是很小的正值,目的是提高成形過程的穩定性。 紡絲原液是兼具粘性和彈性的彈粘體。原液從噴絲孔壓出時,有孔口脹大效應(巴勒斯效應),使擠出細流的直徑大於噴絲孔孔徑。濕紡過程中,脹大比一般為1~2。 在(zai)第(di)一(yi)導(dao)絲(si)盤(pan)的(de)拉(la)伸(shen)力(li)作(zuo)用(yong)下(xia),擠(ji)出(chu)細(xi)流(liu)在(zai)越(yue)過(guo)最(zui)大(da)直(zhi)徑(jing)後(hou)逐(zhu)漸(jian)變(bian)細(xi),細(xi)化(hua)過(guo)程(cheng)一(yi)直(zhi)持(chi)續(xu)到(dao)原(yuan)液(ye)細(xi)流(liu)完(wan)全(quan)固(gu)化(hua)為(wei)止(zhi)。濕(shi)紡(fang)中(zhong)細(xi)流(liu)直(zhi)徑(jing)的(de)變(bian)化(hua)不(bu)僅(jin)是(shi)拉(la)伸(shen)形(xing)變(bian)的(de)結(jie)果(guo),而(er)且(qie)還(hai)與(yu)質(zhi)量(liang)傳(chuan)遞(di)過(guo)程(cheng)有(you)關(guan)。從(cong)噴(pen)絲(si)頭(tou)到(dao)固(gu)化(hua)點(dian)的(de)一(yi)段(duan)紡(fang)程(cheng)為(wei)纖(xian)維(wei)成(cheng)形(xing)區(qu),是(shi)纖(xian)維(wei)結(jie)構(gou)形(xing)成(cheng)的(de)關(guan)鍵(jian)區(qu)域(yu)。 濕(shi)紡(fang)初(chu)生(sheng)纖(xian)維(wei)由(you)於(yu)含(han)有(you)大(da)量(liang)液(ye)體(ti)而(er)處(chu)於(yu)溶(rong)脹(zhang)狀(zhuang)態(tai)。大(da)分(fen)子(zi)具(ju)有(you)很(hen)大(da)的(de)活(huo)動(dong)性(xing),而(er)且(qie)取(qu)向(xiang)度(du)很(hen)低(di),其(qi)形(xing)態(tai)結(jie)構(gou)與(yu)紡(fang)絲(si)工(gong)藝(yi)條(tiao)件(jian)關(guan)係(xi)極(ji)為(wei)密(mi)切(qie)。選(xuan)擇(ze)和(he)控(kong)製(zhi)紡(fang)絲(si)工(gong)藝(yi)條(tiao)件(jian),可(ke)製(zhi)得(de)不(bu)同(tong)橫(heng)截(jie)麵(mian)形(xing)狀(zhuang)或(huo)特(te)殊(shu)毛(mao)細(xi)孔(kong)結(jie)構(gou)和(he)特(te)殊(shu)性(xing)能(neng)的(de)纖(xian)維(wei)。 濕紡有各種不同的成形方式,紡絲機也有各種不同的結構。例如有單浴法或雙浴法,有深浴法或淺浴法,有漏鬥成形或管中成形等. 濕(shi)法(fa)長(chang)絲(si)紡(fang)絲(si)機(ji)的(de)卷(juan)繞(rao)裝(zhuang)置(zhi)有(you)離(li)心(xin)罐(guan)式(shi)或(huo)筒(tong)管(guan)式(shi)。紡(fang)製(zhi)短(duan)纖(xian)維(wei)時(shi)通(tong)常(chang)采(cai)用(yong)紡(fang)絲(si)後(hou)處(chu)理(li)聯(lian)合(he)機(ji),各(ge)紡(fang)絲(si)部(bu)位(wei)成(cheng)形(xing)後(hou)的(de)初(chu)生(sheng)纖(xian)維(wei)被(bei)集(ji)合(he)成(cheng)束(shu),連(lian)續(xu)進(jin)行(xing)後(hou)處(chu)理(li)。 濕紡不僅需要種類繁多、體積龐大的原液製備和紡前準備設備,而且還要有凝固浴、循環及回收設備,其工藝流程複雜、廠房建築和設備投資費用大、紡(fang)絲(si)速(su)度(du)低(di),因(yin)此(ci)成(cheng)本(ben)較(jiao)高(gao)。製(zhi)造(zao)切(qie)段(duan)纖(xian)維(wei)時(shi)可(ke)采(cai)用(yong)數(shu)萬(wan)孔(kong)的(de)噴(pen)絲(si)頭(tou)或(huo)集(ji)裝(zhuang)噴(pen)絲(si)頭(tou)來(lai)提(ti)高(gao)生(sheng)產(chan)能(neng)力(li)。一(yi)般(ban)隻(zhi)有(you)不(bu)能(neng)用(yong)熔(rong)體(ti)紡(fang)絲(si)的(de)合(he)成(cheng)纖(xian)維(wei),例(li)如(ru)聚(ju)丙(bing)烯(xi)腈(jing)纖(xian)維(wei)和(he)聚(ju)乙(yi)烯(xi)醇(chun)纖(xian)維(wei),才(cai)適(shi)於(yu)用(yong)高(gao)聚(ju)物(wu)溶(rong)液(ye)濕(shi)紡(fang)生(sheng)產(chan)切(qie)段(duan)纖(xian)維(wei)和(he)長(chang)絲(si)束(shu)。
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